Edit in JSFiddle

div {
  border: 1px solid black;
  padding: 5px;
  margin: 5px 10px;
  background-color: pink;
}

.ex1:hover {outline-color: invert;}
.ex2:hover {outline-color: blue;}
.ex3:hover {outline-color: rgba(255,0,0,0.5);}

div:hover {
  outline-offset : 5px;
  outline-style: solid;
  outline-width: 10px;
}
<!DOCTYPE html>
<html lang="ko">
  <head></head>
  <body>
    <p>요소에 마우스를 올리세요</p>
    <div class="ex1">outline-color: invert;</div>
    <div class="ex2">outline-color: blue;</div>
    <div class="ex3">outline-color: rgba(255,0,0,0.5);</div>
  </body>
</html>