Edit in JSFiddle

<p>
  This is the <a href="https://developer.mozilla.org/en-US/docs/Web/CSS/position#Sticky_positioning" target="_blank">demo from MDN</a>. CSS <code>position: sticky</code> is supported in Firefox, Safari, and Chrome Canary (56+).
</p>

<hr />

<div>
  <dl>
    <dt>A</dt>
    <dd>Andrew W.K.</dd>
    <dd>Apparat</dd>
    <dd>Arcade Fire</dd>
    <dd>At The Drive-In</dd>
    <dd>Aziz Ansari</dd>
  </dl>
  <dl>
    <dt>C</dt>
    <dd>Chromeo</dd>
    <dd>Common</dd>
    <dd>Converge</dd>
    <dd>Crystal Castles</dd>
    <dd>Cursive</dd>
  </dl>
  <dl>
    <dt>E</dt>
    <dd>Explosions In The Sky</dd>
  </dl>
  <dl>
    <dt>T</dt>
    <dd>Ted Leo & The Pharmacists</dd>
    <dd>T-Pain</dd>
    <dd>Thrice</dd>
    <dd>TV On The Radio</dd>
    <dd>Two Gallants</dd>
  </dl>
</div>

* {
  box-sizing: border-box;
}

body {
  font: bold 18px/21px Helvetica, Arial, sans-serif;
}

p {
  font-weight: normal;
  background: #FFF59D;
  padding: .8em;
}

a {
  color: #07c;
}

dl {
  margin: 0;
  padding: 24px 0 0 0;
}

dt {
  background: #B8C1C8;
  border-bottom: 1px solid #989EA4;
  border-top: 1px solid #717D85;
  color: #FFF;
  margin: 0;
  padding: 2px 0 0 12px;
  position: -webkit-sticky;
  position: sticky;
  top: -1px;
}

dd {
  font: bold 20px/45px Helvetica, Arial, sans-serif;
  margin: 0;
  padding: 0 0 0 12px;
  white-space: nowrap;
}

dd + dd {
  border-top: 1px solid #CCC
}